Biocatalytic enantiomeric resolution of L-menthol from an eight isomeric menthol mixture through transesterification

D. Brady; S. Reddy; B. Mboniswa; L.H Steenkamp; A.L. Rousseau; Christopher Parkinson; J. Chaplin; R.K. Mitra; T. Moutlana; S.F. Marais; N.S. Gardiner

doi:10.1016/j.molcatb.2011.10.011

Biocatalytic enantiomeric resolution of L-menthol from an eight isomeric menthol mixture through transesterification

D. Brady, S. Reddy, B. Mboniswa, L.H Steenkamp, A.L. Rousseau, Christopher Parkinson, J. Chaplin, R.K. Mitra, T. Moutlana, S.F. Marais, N.S. Gardiner

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

A single isomer in an eight isomer menthol mixture was acylated through a lipase mediated transesterification. The isomer selected was the commercially attractive L-menthol. This protocol constitutes a simple method for selecting a commercially attractive isomer from a complex mixture to enable production of the pure form.

Original language	English
Pages (from-to)	1-10
Number of pages	10
Journal	Journal of Molecular Catalysis - B Enzymatic
Volume	75
DOIs	https://doi.org/10.1016/j.molcatb.2011.10.011
Publication status	Published - Mar 2012

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Brady, D., Reddy, S., Mboniswa, B., Steenkamp, L. H., Rousseau, A. L., Parkinson, C., Chaplin, J., Mitra, R. K., Moutlana, T., Marais, S. F., & Gardiner, N. S. (2012). Biocatalytic enantiomeric resolution of L-menthol from an eight isomeric menthol mixture through transesterification. Journal of Molecular Catalysis - B Enzymatic, 75, 1-10. https://doi.org/10.1016/j.molcatb.2011.10.011

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abstract = "A single isomer in an eight isomer menthol mixture was acylated through a lipase mediated transesterification. The isomer selected was the commercially attractive L-menthol. This protocol constitutes a simple method for selecting a commercially attractive isomer from a complex mixture to enable production of the pure form.",

keywords = "Transesterification, lipase, diastereomeric, enantiomeric, BSTR, pseudomonas",

author = "D. Brady and S. Reddy and B. Mboniswa and L.H Steenkamp and A.L. Rousseau and Christopher Parkinson and J. Chaplin and R.K. Mitra and T. Moutlana and S.F. Marais and N.S. Gardiner",

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Brady, D, Reddy, S, Mboniswa, B, Steenkamp, LH, Rousseau, AL, Parkinson, C, Chaplin, J, Mitra, RK, Moutlana, T, Marais, SF & Gardiner, NS 2012, 'Biocatalytic enantiomeric resolution of L-menthol from an eight isomeric menthol mixture through transesterification', Journal of Molecular Catalysis - B Enzymatic, vol. 75, pp. 1-10. https://doi.org/10.1016/j.molcatb.2011.10.011

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T1 - Biocatalytic enantiomeric resolution of L-menthol from an eight isomeric menthol mixture through transesterification

AU - Brady, D.

AU - Reddy, S.

AU - Mboniswa, B.

AU - Steenkamp, L.H

AU - Rousseau, A.L.

AU - Parkinson, Christopher

AU - Chaplin, J.

AU - Mitra, R.K.

AU - Moutlana, T.

AU - Marais, S.F.

AU - Gardiner, N.S.

N1 - Imported on 12 Apr 2017 - DigiTool details were: month (773h) = March; Journal title (773t) = Journal of Molecular Catalysis B: Enzymatic. ISSNs: 1381-1177;

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AB - A single isomer in an eight isomer menthol mixture was acylated through a lipase mediated transesterification. The isomer selected was the commercially attractive L-menthol. This protocol constitutes a simple method for selecting a commercially attractive isomer from a complex mixture to enable production of the pure form.

KW - Transesterification, lipase, diastereomeric, enantiomeric, BSTR, pseudomonas

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DO - 10.1016/j.molcatb.2011.10.011

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JO - Journal of Molecular Catalysis - B Enzymatic

JF - Journal of Molecular Catalysis - B Enzymatic

ER -

Biocatalytic enantiomeric resolution of L-menthol from an eight isomeric menthol mixture through transesterification

Abstract

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