Electron correlation effects in the valence shell photoelectron spectra of haloethenes

A. W. Potts, J. M. Benson, I. Novak, W. A. Svensson

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

Calculations have show that ionization from the inner valence shells of haloethenes cannot be treated on a one-electron basis and that photoelectron spectra should show additional bands corresponding to final ionized states of mixed character. The spectra of a range of haloethenes have been recorded using synchrotron radiation with photon energies of up to 75 eV and the inner valence shell spectra have been shown to be in good agreement with predictions. The measurements have also been used to extend existing photoelectron assignments providing complete valence shell assignments for the molecules studied.

Original languageEnglish
Pages (from-to)253-260
Number of pages8
JournalChemical Physics
Volume115
Issue number2
DOIs
Publication statusPublished - 15 Jul 1987

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