Electronic structure of two phosphorus compounds

Igor Novak; Branka Kovac

doi:10.1016/j.elspec.2010.06.006

Electronic structure of two phosphorus compounds

Igor Novak, Branka Kovac

Research output: Contribution to journal › Article › peer-review

8 Downloads (Pure)

Abstract

The electronic structures of tri-2-furanyl-phosphine (I) and 1,2-bis(dimethoxyphosphoryl)benzene (II) have been investigated by HeI and HeII UV photoelectron spectroscopy (UPS) and quantum chemical calculations. Their electronic structures are discussed in the framework of their chemical properties and practical applications with special reference to the extent of intramolecular interactions. We have also rationalized the observed increased shielding of phosphorus in 31P NMR spectra of TFP.

Original language	English
Pages (from-to)	76-80
Number of pages	5
Journal	Journal of Electron Spectroscopy and Related Phenomena
Volume	182
Issue number	1-2
DOIs	https://doi.org/10.1016/j.elspec.2010.06.006
Publication status	Published - Nov 2010

Access to Document

10.1016/j.elspec.2010.06.006

phosphorus.docAccepted author manuscript, 565 KB

Cite this

@article{a5879072b6814e098d53ec4c974edc09,

title = "Electronic structure of two phosphorus compounds",

abstract = "The electronic structures of tri-2-furanyl-phosphine (I) and 1,2-bis(dimethoxyphosphoryl)benzene (II) have been investigated by HeI and HeII UV photoelectron spectroscopy (UPS) and quantum chemical calculations. Their electronic structures are discussed in the framework of their chemical properties and practical applications with special reference to the extent of intramolecular interactions. We have also rationalized the observed increased shielding of phosphorus in 31P NMR spectra of TFP.",

keywords = "Open access version available, Phosphorus compounds, Photelectron spectroscopy",

author = "Igor Novak and Branka Kovac",

note = "Imported on 12 Apr 2017 - DigiTool details were: month (773h) = November 2010; Journal title (773t) = Journal of Electron Spectroscopy and Related Phenomena. ISSNs: 0368-2048; ",

year = "2010",

month = nov,

doi = "10.1016/j.elspec.2010.06.006",

language = "English",

volume = "182",

pages = "76--80",

journal = "Journal of Electron Spectroscopy and Related Phenomena",

issn = "0368-2048",

publisher = "Elsevier",

number = "1-2",

}

TY - JOUR

T1 - Electronic structure of two phosphorus compounds

AU - Novak, Igor

AU - Kovac, Branka

N1 - Imported on 12 Apr 2017 - DigiTool details were: month (773h) = November 2010; Journal title (773t) = Journal of Electron Spectroscopy and Related Phenomena. ISSNs: 0368-2048;

PY - 2010/11

Y1 - 2010/11

N2 - The electronic structures of tri-2-furanyl-phosphine (I) and 1,2-bis(dimethoxyphosphoryl)benzene (II) have been investigated by HeI and HeII UV photoelectron spectroscopy (UPS) and quantum chemical calculations. Their electronic structures are discussed in the framework of their chemical properties and practical applications with special reference to the extent of intramolecular interactions. We have also rationalized the observed increased shielding of phosphorus in 31P NMR spectra of TFP.

AB - The electronic structures of tri-2-furanyl-phosphine (I) and 1,2-bis(dimethoxyphosphoryl)benzene (II) have been investigated by HeI and HeII UV photoelectron spectroscopy (UPS) and quantum chemical calculations. Their electronic structures are discussed in the framework of their chemical properties and practical applications with special reference to the extent of intramolecular interactions. We have also rationalized the observed increased shielding of phosphorus in 31P NMR spectra of TFP.

KW - Open access version available

KW - Phosphorus compounds

KW - Photelectron spectroscopy

U2 - 10.1016/j.elspec.2010.06.006

DO - 10.1016/j.elspec.2010.06.006

M3 - Article

SN - 0368-2048

VL - 182

SP - 76

EP - 80

JO - Journal of Electron Spectroscopy and Related Phenomena

JF - Journal of Electron Spectroscopy and Related Phenomena

IS - 1-2

ER -

Electronic structure of two phosphorus compounds

Abstract

Access to Document

Fingerprint

Cite this