Electronic structures of very strong, neutral bases

Igor Novak, Xuming Wei, Wee Shong Chin

Research output: Contribution to journalArticle

34 Citations (Scopus)

Abstract

UV photoelectron spectroscopy was used to investigate the electronic structure of 10 very strong, neutral amine bases of guanidine and phosphazene type. The spectral assignment was based on the band intensities, Hel/Hell band intensity changes (when available), comparison with the spectra of related compounds and MO calculations. The relative importance of various factors influencing basicity is discussed.

Original languageEnglish
Pages (from-to)1783-1788
Number of pages6
JournalJournal of Physical Chemistry A
Volume105
Issue number10
Publication statusPublished - 2001

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Guanidine
Photoelectron spectroscopy
Alkalinity
Ultraviolet spectroscopy
Electronic structure
Amines
phosphazene
electronic structure
guanidines
amines
photoelectron spectroscopy

Cite this

Novak, Igor ; Wei, Xuming ; Chin, Wee Shong. / Electronic structures of very strong, neutral bases. In: Journal of Physical Chemistry A. 2001 ; Vol. 105, No. 10. pp. 1783-1788.
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Novak, I, Wei, X & Chin, WS 2001, 'Electronic structures of very strong, neutral bases', Journal of Physical Chemistry A, vol. 105, no. 10, pp. 1783-1788.

Electronic structures of very strong, neutral bases. / Novak, Igor; Wei, Xuming; Chin, Wee Shong.

In: Journal of Physical Chemistry A, Vol. 105, No. 10, 2001, p. 1783-1788.

Research output: Contribution to journalArticle

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