Electronic structures of very strong, neutral bases

Igor Novak; Xuming Wei; Wee Shong Chin

doi:10.1021/jp003430k

Electronic structures of very strong, neutral bases

Igor Novak, Xuming Wei, Wee Shong Chin

Agricultural, Environmental and Veterinary Sciences

National University of Singapore

Research output: Contribution to journal › Article › peer-review

34 Citations (Scopus)

Abstract

UV photoelectron spectroscopy was used to investigate the electronic structure of 10 very strong, neutral amine bases of guanidine and phosphazene type. The spectral assignment was based on the band intensities, Hel/Hell band intensity changes (when available), comparison with the spectra of related compounds and MO calculations. The relative importance of various factors influencing basicity is discussed.

Original language	English
Pages (from-to)	1783-1788
Number of pages	6
Journal	Journal of Physical Chemistry A
Volume	105
Issue number	10
DOIs	https://doi.org/10.1021/jp003430k
Publication status	Published - 2001

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title = "Electronic structures of very strong, neutral bases",

abstract = "UV photoelectron spectroscopy was used to investigate the electronic structure of 10 very strong, neutral amine bases of guanidine and phosphazene type. The spectral assignment was based on the band intensities, Hel/Hell band intensity changes (when available), comparison with the spectra of related compounds and MO calculations. The relative importance of various factors influencing basicity is discussed.",

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AU - Wei, Xuming

AU - Chin, Wee Shong

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AB - UV photoelectron spectroscopy was used to investigate the electronic structure of 10 very strong, neutral amine bases of guanidine and phosphazene type. The spectral assignment was based on the band intensities, Hel/Hell band intensity changes (when available), comparison with the spectra of related compounds and MO calculations. The relative importance of various factors influencing basicity is discussed.

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JF - Journal of Physical Chemistry A

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Electronic structures of very strong, neutral bases

Abstract

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