TY - JOUR
T1 - First syntheses of fused pyrroloporphyrins
AU - Jaquinod, Laurent
AU - Gros, Claude
AU - Olmstead, Marilyn M.
AU - Antolovich, Michael
AU - Smith, Kevin M.
PY - 1996/1/1
Y1 - 1996/1/1
N2 - (2-Nitro-5,10,15,20-tetraphenylporphyrinato)nickel(II) reacts with α-isocyanoacetic esters in the presence of DBU to give the first β-fused pyrroloporphyrins, the pyrrole ring in the fused system being shown to undergo typical pyrrole-type chemistry; the corresponding zinc(II) complex affords a novel cyclopropanochlorin (characterized by X-ray crystallography), when treated with an α-isocyanoacetic ester.
AB - (2-Nitro-5,10,15,20-tetraphenylporphyrinato)nickel(II) reacts with α-isocyanoacetic esters in the presence of DBU to give the first β-fused pyrroloporphyrins, the pyrrole ring in the fused system being shown to undergo typical pyrrole-type chemistry; the corresponding zinc(II) complex affords a novel cyclopropanochlorin (characterized by X-ray crystallography), when treated with an α-isocyanoacetic ester.
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U2 - 10.1039/cc9960001475
DO - 10.1039/cc9960001475
M3 - Article
AN - SCOPUS:0002425255
SN - 1359-7345
SP - 1475
EP - 1476
JO - Chemical Communications
JF - Chemical Communications
IS - 12
ER -