First syntheses of fused pyrroloporphyrins

Laurent Jaquinod; Claude Gros; Marilyn M. Olmstead; Michael Antolovich; Kevin M. Smith

doi:10.1039/cc9960001475

First syntheses of fused pyrroloporphyrins

Laurent Jaquinod
, Claude Gros
, Marilyn M. Olmstead
, Michael Antolovich
, Kevin M. Smith

University of California

Research output: Contribution to journal › Article › peer-review

89 Citations (Scopus)

Abstract

(2-Nitro-5,10,15,20-tetraphenylporphyrinato)nickel(II) reacts with α-isocyanoacetic esters in the presence of DBU to give the first β-fused pyrroloporphyrins, the pyrrole ring in the fused system being shown to undergo typical pyrrole-type chemistry; the corresponding zinc(II) complex affords a novel cyclopropanochlorin (characterized by X-ray crystallography), when treated with an α-isocyanoacetic ester.

Original language	English
Pages (from-to)	1475-1476
Number of pages	2
Journal	Chemical Communications
Issue number	12
DOIs	https://doi.org/10.1039/cc9960001475
Publication status	Published - 01 Jan 1996

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T1 - First syntheses of fused pyrroloporphyrins

AU - Jaquinod, Laurent

AU - Gros, Claude

AU - Olmstead, Marilyn M.

AU - Antolovich, Michael

AU - Smith, Kevin M.

PY - 1996/1/1

Y1 - 1996/1/1

N2 - (2-Nitro-5,10,15,20-tetraphenylporphyrinato)nickel(II) reacts with α-isocyanoacetic esters in the presence of DBU to give the first β-fused pyrroloporphyrins, the pyrrole ring in the fused system being shown to undergo typical pyrrole-type chemistry; the corresponding zinc(II) complex affords a novel cyclopropanochlorin (characterized by X-ray crystallography), when treated with an α-isocyanoacetic ester.

AB - (2-Nitro-5,10,15,20-tetraphenylporphyrinato)nickel(II) reacts with α-isocyanoacetic esters in the presence of DBU to give the first β-fused pyrroloporphyrins, the pyrrole ring in the fused system being shown to undergo typical pyrrole-type chemistry; the corresponding zinc(II) complex affords a novel cyclopropanochlorin (characterized by X-ray crystallography), when treated with an α-isocyanoacetic ester.

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UR - https://www.scopus.com/pages/publications/0002425255#tab=citedBy

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EP - 1476

JO - Chemical Communications

JF - Chemical Communications

IS - 12

ER -

First syntheses of fused pyrroloporphyrins

Abstract

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