H NMR evidence for the formation of vinyllead triacetates. The reactions of vinylmercury, vinyltin, and vinylboronic acids with lead tetraacetate

Christopher J. Parkinson, Martin J. Stoermer

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

Vinylmercury compounds, vinylboronic acids and vinylstannanes undergo rapid metal-lead exchange with lead tetraacetate in deuterochloroform to generate vinyllead triacetates, which have been characterised by their 1H-1H and 207Pb-1H coupling constants. In addition, a number of divinyl and mixed aryl-vinyllead dicarboxylates have been prepared via boron-lead exchange.

Original languageEnglish
Pages (from-to)207-214
Number of pages8
JournalJournal of Organometallic Chemistry
Volume507
Issue number1-2
Publication statusPublished - 25 Jan 1996

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