TY - JOUR
T1 - H NMR evidence for the formation of vinyllead triacetates. The reactions of vinylmercury, vinyltin, and vinylboronic acids with lead tetraacetate
AU - Parkinson, Christopher J.
AU - Stoermer, Martin J.
PY - 1996/1/25
Y1 - 1996/1/25
N2 - Vinylmercury compounds, vinylboronic acids and vinylstannanes undergo rapid metal-lead exchange with lead tetraacetate in deuterochloroform to generate vinyllead triacetates, which have been characterised by their 1H-1H and 207Pb-1H coupling constants. In addition, a number of divinyl and mixed aryl-vinyllead dicarboxylates have been prepared via boron-lead exchange.
AB - Vinylmercury compounds, vinylboronic acids and vinylstannanes undergo rapid metal-lead exchange with lead tetraacetate in deuterochloroform to generate vinyllead triacetates, which have been characterised by their 1H-1H and 207Pb-1H coupling constants. In addition, a number of divinyl and mixed aryl-vinyllead dicarboxylates have been prepared via boron-lead exchange.
KW - Boron
KW - Boronic acid
KW - Lead
KW - Mercury
KW - Nuclear magnetic resonance
KW - Tin
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U2 - 10.1016/0022-328X(95)05746-C
DO - 10.1016/0022-328X(95)05746-C
M3 - Article
AN - SCOPUS:0030600613
SN - 0022-328X
VL - 507
SP - 207
EP - 214
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 1-2
ER -