Highly enantioselective phenyl transfer to aryl aldehydes catalyzed by easily accessible chiral tertiary aminonaphthol

Jian Xin Ji; Jing Wu; Terry T.L. Au-Yeung; Chiu Wing Yip; Richard K. Haynes; Albert S.C. Chan

doi:10.1021/jo048395i

Highly enantioselective phenyl transfer to aryl aldehydes catalyzed by easily accessible chiral tertiary aminonaphthol

Jian Xin Ji, Jing Wu, Terry T.L. Au-Yeung, Chiu Wing Yip, Richard K. Haynes, Albert S.C. Chan

The Hong Kong Polytechnic University

Research output: Contribution to journal › Article › peer-review

117 Citations (Scopus)

Abstract

(Chemical Equation Presented) A new chiral tertiary aminonaphthol ligand 3b served as a highly efficient ligand for the asymmetric catalytic phenyl transfer to aromatic aldehydes and a variety of chiral diarylmethanols was prepared in high ee values (ee up to 99%) and chemical yields. The straightforward syntheses of both 3b and its enantiomer provide an excellent opportunity for large-scale applications.

Original language	English
Pages (from-to)	1093-1095
Number of pages	3
Journal	Journal of Organic Chemistry
Volume	70
Issue number	3
DOIs	https://doi.org/10.1021/jo048395i
Publication status	Published - 04 Feb 2005

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abstract = "(Chemical Equation Presented) A new chiral tertiary aminonaphthol ligand 3b served as a highly efficient ligand for the asymmetric catalytic phenyl transfer to aromatic aldehydes and a variety of chiral diarylmethanols was prepared in high ee values (ee up to 99%) and chemical yields. The straightforward syntheses of both 3b and its enantiomer provide an excellent opportunity for large-scale applications.",

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T1 - Highly enantioselective phenyl transfer to aryl aldehydes catalyzed by easily accessible chiral tertiary aminonaphthol

AU - Ji, Jian Xin

AU - Wu, Jing

AU - Au-Yeung, Terry T.L.

AU - Yip, Chiu Wing

AU - Haynes, Richard K.

AU - Chan, Albert S.C.

PY - 2005/2/4

Y1 - 2005/2/4

N2 - (Chemical Equation Presented) A new chiral tertiary aminonaphthol ligand 3b served as a highly efficient ligand for the asymmetric catalytic phenyl transfer to aromatic aldehydes and a variety of chiral diarylmethanols was prepared in high ee values (ee up to 99%) and chemical yields. The straightforward syntheses of both 3b and its enantiomer provide an excellent opportunity for large-scale applications.

AB - (Chemical Equation Presented) A new chiral tertiary aminonaphthol ligand 3b served as a highly efficient ligand for the asymmetric catalytic phenyl transfer to aromatic aldehydes and a variety of chiral diarylmethanols was prepared in high ee values (ee up to 99%) and chemical yields. The straightforward syntheses of both 3b and its enantiomer provide an excellent opportunity for large-scale applications.

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ER -

Highly enantioselective phenyl transfer to aryl aldehydes catalyzed by easily accessible chiral tertiary aminonaphthol

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