Matrix isolation in photoelectron spectroscopy

A. W. Potts, S. Anjum, J. Benson, I. Novak

Research output: Contribution to journalArticle

Abstract

A range of volatile inorganic species have been trapped in a zinc matrix using the process of co-condensation and their UV photoelectron spectra have been recorded. These are seen to correspond to broadened versions of the molecular spectra with ionization energies subject to small polarization shifts. Differences in the ionization energies measured for low doses of condensate and those measured for higher doses are interpreted in terms of isolation of small and large clusters within the zinc matrix.

Original languageEnglish
Pages (from-to)281-288
Number of pages8
JournalChemical Physics
Volume161
Issue number1-2
DOIs
Publication statusPublished - 01 Apr 1992

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