Photoelectron Spectra of Some Organozinc Compounds

Mat Barwick, Tareq Abu-Izneid, Igor Novak, Branka Kovac

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Abstract

The electronic structures of bis(pentafluorophenyl)zinc (I) and dichloro(N,N,N',N'-tetramethylethylenediamine)zinc(II) (II) have been investigated by HeI and HeII UV photoelectron spectroscopy (UPS) and DFT/OVGF calculations. We discuss the properties of Zn-aryl and Zn-N bonds on the basis of spectroscopic evidence i.e. the nature of metal-ligand bonding. Our study is the first reported one on the photoelectron spectra of zinc-aryl complex.
Original languageEnglish
Pages (from-to)79-81
Number of pages3
JournalChemical Physics Letters
Volume460
Issue number1-3
DOIs
Publication statusPublished - 2008

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Photoelectrons
Zinc
photoelectrons
zinc
Photoelectron spectroscopy
Ultraviolet spectroscopy
Discrete Fourier transforms
Electronic structure
Metals
photoelectron spectroscopy
electronic structure
Ligands
ligands
metals

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Barwick, Mat ; Abu-Izneid, Tareq ; Novak, Igor ; Kovac, Branka. / Photoelectron Spectra of Some Organozinc Compounds. In: Chemical Physics Letters. 2008 ; Vol. 460, No. 1-3. pp. 79-81.
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Photoelectron Spectra of Some Organozinc Compounds. / Barwick, Mat; Abu-Izneid, Tareq; Novak, Igor; Kovac, Branka.

In: Chemical Physics Letters, Vol. 460, No. 1-3, 2008, p. 79-81.

Research output: Contribution to journalArticle

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AU - Abu-Izneid, Tareq

AU - Novak, Igor

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AB - The electronic structures of bis(pentafluorophenyl)zinc (I) and dichloro(N,N,N',N'-tetramethylethylenediamine)zinc(II) (II) have been investigated by HeI and HeII UV photoelectron spectroscopy (UPS) and DFT/OVGF calculations. We discuss the properties of Zn-aryl and Zn-N bonds on the basis of spectroscopic evidence i.e. the nature of metal-ligand bonding. Our study is the first reported one on the photoelectron spectra of zinc-aryl complex.

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KW - Organometallic compounds

KW - Photoelectron spectroscopy

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