Photoelectron spectroscopic study of sulfur-sulfur interactions in macrocyclic thioethers

I. Novak, S. C. Ng, A. W. Potts

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)

Abstract

He I photoelectron spectra of 1,4,7-trithiacyclononane, 1,4,7-trithiacyclodecane, 1,4,7,10-tetrathiacyclododecane, 1,4,8,11-tetrathiacyclotetradecane, 1,5,9,13-tetrathiacyclohexadecane and 1,5,9,13-tetrathiacyclohexadecane-3,11-diol were measured and used to obtain information on sulphur-sulphur lone pair interactions. Comparisons with spectra of oxygen macrocyclic analogs allowed several general trends in electronic structures of these ligands to be established.

Original languageEnglish
Pages (from-to)353-356
Number of pages4
JournalSpectrochimica Acta Part A: Molecular Spectroscopy
Volume50
Issue number2
DOIs
Publication statusPublished - 1994

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