Photoelectron spectroscopy of natural products. Part 1. Polypodanes

Lien Hoa D. Nguyen; Leslie J. Harrison; Igor Novak; Anthony W. Potts

doi:10.1002/(SICI)1099-1395(199910)12:10<765::AID-POC189>3.0.CO;2-N

Photoelectron spectroscopy of natural products. Part 1. Polypodanes

Lien Hoa D. Nguyen, Leslie J. Harrison, Igor Novak, Anthony W. Potts

Agricultural, Environmental and Veterinary Sciences

Research output: Contribution to journal › Article › peer-review

Abstract

He I UV photoelectron spectra of four naturally occurring polyenes were measured. The spectra were interpreted on the basis of empirical arguments and semiempirical MO calculations. The results show that through-bond interactions between π-orbitals are discernible in spite of the non-rigid molecular geometry. This work shows that natural products have electronic structures which are of interest to a wider circle of chemists than just those who specialize in natural products.

Original language	English
Pages (from-to)	765-768
Number of pages	4
Journal	Journal of Physical Organic Chemistry
Volume	12
Issue number	10
DOIs	https://doi.org/10.1002/(SICI)1099-1395(199910)12:10<765::AID-POC189>3.0.CO;2-N
Publication status	Published - Oct 1999

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10.1002/(SICI)1099-1395(199910)12:10<765::AID-POC189>3.0.CO;2-N

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title = "Photoelectron spectroscopy of natural products. Part 1. Polypodanes",

abstract = "He I UV photoelectron spectra of four naturally occurring polyenes were measured. The spectra were interpreted on the basis of empirical arguments and semiempirical MO calculations. The results show that through-bond interactions between π-orbitals are discernible in spite of the non-rigid molecular geometry. This work shows that natural products have electronic structures which are of interest to a wider circle of chemists than just those who specialize in natural products.",

keywords = "Natural products, Photoelectron spectra, Polyenes, Polypodanes",

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AU - Potts, Anthony W.

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Y1 - 1999/10

N2 - He I UV photoelectron spectra of four naturally occurring polyenes were measured. The spectra were interpreted on the basis of empirical arguments and semiempirical MO calculations. The results show that through-bond interactions between π-orbitals are discernible in spite of the non-rigid molecular geometry. This work shows that natural products have electronic structures which are of interest to a wider circle of chemists than just those who specialize in natural products.

AB - He I UV photoelectron spectra of four naturally occurring polyenes were measured. The spectra were interpreted on the basis of empirical arguments and semiempirical MO calculations. The results show that through-bond interactions between π-orbitals are discernible in spite of the non-rigid molecular geometry. This work shows that natural products have electronic structures which are of interest to a wider circle of chemists than just those who specialize in natural products.

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KW - Photoelectron spectra

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Photoelectron spectroscopy of natural products. Part 1. Polypodanes

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