Photoelectron spectroscopy of some chlorinated phosphate esters

Igor Novak, Branka Kovac

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Abstract

The electronic structures of ethylenephosphochloridate, 1,2-phenylenephosphochloridate and 2,2,2-trichloro-1,3,2-benzodioxaphosphole have been studied by HeI/HeII photoelectron spectroscopy (UPS) and Green's function calculations. Our results indicate the importance of hyperconjugative interactions between the 5-membered ring and the fused aromatic ring. Some implications of our results for rates of nucleophilic substitution reactions on phosphorus are discussed.
Original languageEnglish
Pages (from-to)12-16
Number of pages5
JournalJournal of Electron Spectroscopy and Related Phenomena
Volume189
DOIs
Publication statusPublished - Aug 2013

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