The use of unconventional water resources is an effective way to alleviate the scarcity of freshwater resources, especially in areas where freshwater is scarce, but reclaimed water is abundant. To explore the reasonable utilization of brackish water and reclaimed water, a pot experiment was carried out to study the risk of secondary soil salinization. The experiment set two salinity levels of brackish water, four mixed irrigation ratios of brackish water and reclaimed water, and freshwater irrigation as the control. The results showed that: (1) Soil moisture content, salt content, pH, ESP, and SAR decreased with the increase in the proportion of reclaimed water in the mixture. (2) Soil exchangeable Ca2+ content under mixed irrigation was higher than that of brackish water irrigation and reclaimed water irrigation. The content was especially significantly higher under the 1:2 mixed irrigation with brackish-reclaimed water. With the increase of the proportion of reclaimed water in the mixture, soil exchangeable Na+ content decreased, and a significant difference was found between treatments. The soil exchangeable K+ decreased at first and then increased, while the soil exchangeable Ca2+ increased at first and then decreased. The trend of the change of soil exchangeable Mg2+ content was similar to that of soil exchangeable Ca2+ content. (3) Based on the soil pH value, there was no risk of soil alkalization in all treatments. Based on ESP, ESP was less than 15% under freshwater irrigation, brackish (3 g/L)-reclaimed water 1:2 mixed irrigation, and reclaimed water irrigation, indicating no risk of alkalization. However, other treatments may cause soil alkalization. (4) At 3 g/L of brackish water, there was a salinization risk when the proportion of reclaimed water in the mixture was less than 1/2, but there was no salinization risk when the proportion was greater than 1/2. At 5 g/L of brackish water, there was a salinization risk under mixed irrigation. Therefore, the mixed irrigation of brackish water and reclaimed water had the risk of secondary soil salinization, and the appropriate salinity and mixing ratio should be selected.