Stereocontrolled synthesis of calyculin A: Construction of the C(15)-C(25) spiroketal unit

Anthony G M Barrett, Jeremy J. Edmunds, Kiyoshi Horita, Christopher J. Parkinson

Research output: Contribution to journalArticle

34 Citations (Scopus)

Abstract

Two concise enantioselective syntheses of the C(15)-C(25) spiroketal unit of calyculin A, using derivatives of allyldiisopinocampheylborane efficieintly to control 1,2- and 1,3-diol stereochemistries, are reported.

Original languageEnglish
Pages (from-to)1236-1238
Number of pages3
JournalJournal of the Chemical Society, Chemical Communications
Issue number17
DOIs
Publication statusPublished - 1992

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