Stereocontrolled synthesis of calyculin A: Construction of the C(15)-C(25) spiroketal unit

Anthony G M Barrett; Jeremy J. Edmunds; Kiyoshi Horita; Christopher J. Parkinson

doi:10.1039/C39920001236

Stereocontrolled synthesis of calyculin A: Construction of the C(15)-C(25) spiroketal unit

Anthony G M Barrett
, Jeremy J. Edmunds
, Kiyoshi Horita
, Christopher J. Parkinson

Dentistry and Medical Sciences

Colorado State University
Northwestern University

Research output: Contribution to journal › Article › peer-review

35 Citations (Scopus)

Abstract

Two concise enantioselective syntheses of the C(15)-C(25) spiroketal unit of calyculin A, using derivatives of allyldiisopinocampheylborane efficieintly to control 1,2- and 1,3-diol stereochemistries, are reported.

Original language	English
Pages (from-to)	1236-1238
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	17
DOIs	https://doi.org/10.1039/C39920001236
Publication status	Published - 1992

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10.1039/C39920001236

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title = "Stereocontrolled synthesis of calyculin A: Construction of the C(15)-C(25) spiroketal unit",

abstract = "Two concise enantioselective syntheses of the C(15)-C(25) spiroketal unit of calyculin A, using derivatives of allyldiisopinocampheylborane efficieintly to control 1,2- and 1,3-diol stereochemistries, are reported.",

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year = "1992",

doi = "10.1039/C39920001236",

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journal = "Journal of the Chemical Society, Chemical Communications",

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AU - Barrett, Anthony G M

AU - Edmunds, Jeremy J.

AU - Horita, Kiyoshi

AU - Parkinson, Christopher J.

PY - 1992

Y1 - 1992

N2 - Two concise enantioselective syntheses of the C(15)-C(25) spiroketal unit of calyculin A, using derivatives of allyldiisopinocampheylborane efficieintly to control 1,2- and 1,3-diol stereochemistries, are reported.

AB - Two concise enantioselective syntheses of the C(15)-C(25) spiroketal unit of calyculin A, using derivatives of allyldiisopinocampheylborane efficieintly to control 1,2- and 1,3-diol stereochemistries, are reported.

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DO - 10.1039/C39920001236

M3 - Article

AN - SCOPUS:0026802523

SN - 0022-4936

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JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 17

ER -

Stereocontrolled synthesis of calyculin A: Construction of the C(15)-C(25) spiroketal unit

Abstract

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