The diastereospecific aprotic conjugate addition reactions of allylic anions-mechanistic aspects.

Malcolm R. Binns, Oi Lee Chai, Richard K. Haynes, Andrew A. Katsifis, Paul A. Schober, Simone C. Vonwiller

Research output: Contribution to journalArticlepeer-review

35 Citations (Scopus)

Abstract

A ten-membered cyclic "chair-chair" - or "trans-decalyl"-like TS is proposed to account for the diastereospecific aprotic conjugate addition reactions of allylic carbanions bearing polar, charge-stabilizing groups.

Original languageEnglish
Pages (from-to)1569-1572
Number of pages4
JournalTetrahedron Letters
Volume26
Issue number12
DOIs
Publication statusPublished - 1985

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