The diastereospecific aprotic conjugate addition reactions of allylic anions-mechanistic aspects.

Malcolm R. Binns; Oi Lee Chai; Richard K. Haynes; Andrew A. Katsifis; Paul A. Schober; Simone C. Vonwiller

doi:10.1016/S0040-4039(00)98554-X

The diastereospecific aprotic conjugate addition reactions of allylic anions-mechanistic aspects.

Malcolm R. Binns
, Oi Lee Chai
, Richard K. Haynes
, Andrew A. Katsifis
, Paul A. Schober
, Simone C. Vonwiller

The University of Sydney

Research output: Contribution to journal › Article › peer-review

35 Citations (Scopus)

Abstract

A ten-membered cyclic "chair-chair" - or "trans-decalyl"-like TS is proposed to account for the diastereospecific aprotic conjugate addition reactions of allylic carbanions bearing polar, charge-stabilizing groups.

Original language	English
Pages (from-to)	1569-1572
Number of pages	4
Journal	Tetrahedron Letters
Volume	26
Issue number	12
DOIs	https://doi.org/10.1016/S0040-4039(00)98554-X
Publication status	Published - 1985

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title = "The diastereospecific aprotic conjugate addition reactions of allylic anions-mechanistic aspects.",

abstract = "A ten-membered cyclic {"}chair-chair{"} - or {"}trans-decalyl{"}-like TS is proposed to account for the diastereospecific aprotic conjugate addition reactions of allylic carbanions bearing polar, charge-stabilizing groups.",

author = "Binns, \{Malcolm R.\} and Chai, \{Oi Lee\} and Haynes, \{Richard K.\} and Katsifis, \{Andrew A.\} and Schober, \{Paul A.\} and Vonwiller, \{Simone C.\}",

note = "Funding Information: Acknowledgement: We thank the Australian Research Grants Schemefor financial",

year = "1985",

doi = "10.1016/S0040-4039(00)98554-X",

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AU - Binns, Malcolm R.

AU - Chai, Oi Lee

AU - Haynes, Richard K.

AU - Katsifis, Andrew A.

AU - Schober, Paul A.

AU - Vonwiller, Simone C.

N1 - Funding Information: Acknowledgement: We thank the Australian Research Grants Schemefor financial

PY - 1985

Y1 - 1985

N2 - A ten-membered cyclic "chair-chair" - or "trans-decalyl"-like TS is proposed to account for the diastereospecific aprotic conjugate addition reactions of allylic carbanions bearing polar, charge-stabilizing groups.

AB - A ten-membered cyclic "chair-chair" - or "trans-decalyl"-like TS is proposed to account for the diastereospecific aprotic conjugate addition reactions of allylic carbanions bearing polar, charge-stabilizing groups.

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UR - https://www.scopus.com/pages/publications/0000251480#tab=citedBy

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DO - 10.1016/S0040-4039(00)98554-X

M3 - Article

AN - SCOPUS:0000251480

SN - 0040-4039

VL - 26

SP - 1569

EP - 1572

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 12

ER -

The diastereospecific aprotic conjugate addition reactions of allylic anions-mechanistic aspects.

Abstract

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