Abstract
The He I and He II photoelectron spectra of 4‐methylmorpholine, 4‐morpholinecarbonitrile, and 4‐morpholinepropionitrile have been measured. The electronic structure and heteroatom lone pair interactions, in particular, were analyzed with the aid of HeII/HeI intensity variations, comparison with the spectra of related compounds, and AM1 semiempirical calculations. We present an example of combined inductive and resonance interactions operating in the morpholine ring system.
| Original language | English |
|---|---|
| Pages (from-to) | 29-31 |
| Number of pages | 3 |
| Journal | Heteroatom Chemistry |
| Volume | 6 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 1995 |
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Novak, I., & Kovaĉ, B. (1995). Trans‐annular interactions in morpholines: A photoelectron spectroscopic study. Heteroatom Chemistry, 6(1), 29-31. https://doi.org/10.1002/hc.520060108