Abstract
The He I and He II photoelectron spectra of 4‐methylmorpholine, 4‐morpholinecarbonitrile, and 4‐morpholinepropionitrile have been measured. The electronic structure and heteroatom lone pair interactions, in particular, were analyzed with the aid of HeII/HeI intensity variations, comparison with the spectra of related compounds, and AM1 semiempirical calculations. We present an example of combined inductive and resonance interactions operating in the morpholine ring system.
| Original language | English |
|---|---|
| Pages (from-to) | 29-31 |
| Number of pages | 3 |
| Journal | Heteroatom Chemistry |
| Volume | 6 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 1995 |
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Trans‐annular interactions in morpholines : A photoelectron spectroscopic study. / Novak, Igor; Kovaĉ, Branka.
In: Heteroatom Chemistry, Vol. 6, No. 1, 1995, p. 29-31.Research output: Contribution to journal › Article
TY - JOUR
T1 - Trans‐annular interactions in morpholines
T2 - A photoelectron spectroscopic study
AU - Novak, Igor
AU - Kovaĉ, Branka
PY - 1995
Y1 - 1995
N2 - The He I and He II photoelectron spectra of 4‐methylmorpholine, 4‐morpholinecarbonitrile, and 4‐morpholinepropionitrile have been measured. The electronic structure and heteroatom lone pair interactions, in particular, were analyzed with the aid of HeII/HeI intensity variations, comparison with the spectra of related compounds, and AM1 semiempirical calculations. We present an example of combined inductive and resonance interactions operating in the morpholine ring system.
AB - The He I and He II photoelectron spectra of 4‐methylmorpholine, 4‐morpholinecarbonitrile, and 4‐morpholinepropionitrile have been measured. The electronic structure and heteroatom lone pair interactions, in particular, were analyzed with the aid of HeII/HeI intensity variations, comparison with the spectra of related compounds, and AM1 semiempirical calculations. We present an example of combined inductive and resonance interactions operating in the morpholine ring system.
UR - http://www.scopus.com/inward/record.url?scp=84987564392&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84987564392&partnerID=8YFLogxK
U2 - 10.1002/hc.520060108
DO - 10.1002/hc.520060108
M3 - Article
AN - SCOPUS:84987564392
VL - 6
SP - 29
EP - 31
JO - Heteroatom Chemistry
JF - Heteroatom Chemistry
SN - 1042-7163
IS - 1
ER -