Trans‐annular interactions in morpholines: A photoelectron spectroscopic study

Igor Novak, Branka Kovaĉ

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The He I and He II photoelectron spectra of 4‐methylmorpholine, 4‐morpholinecarbonitrile, and 4‐morpholinepropionitrile have been measured. The electronic structure and heteroatom lone pair interactions, in particular, were analyzed with the aid of HeII/HeI intensity variations, comparison with the spectra of related compounds, and AM1 semiempirical calculations. We present an example of combined inductive and resonance interactions operating in the morpholine ring system.

Original languageEnglish
Pages (from-to)29-31
Number of pages3
JournalHeteroatom Chemistry
Volume6
Issue number1
DOIs
Publication statusPublished - 1995

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