UPS Study of Spirosilane

Igor Novak, Branka Kovac

Research output: Contribution to journalArticle

Abstract

The electronic structure of 2,7-dimethyl-5-silaspiro[4,4]nona-2,7-diene has been investigated byUV photoelectron spectroscopy (UPS). The analysis of the spectra has been performed by DFT andROVGF calculations and comparison with the UPS spectra of related compounds. An unusual '-orbitaldegeneracy in this molecule of C2-symmetry was observed. The spiroconjugation is quenched,and the reasons are discussed
Original languageEnglish
Pages (from-to)217-219
Number of pages3
JournalZeitschrift fur Naturforschung - Section A Journal of Physical Sciences
Volume58a
Issue number4
Publication statusPublished - 2003

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Photoelectron spectroscopy
Discrete Fourier transforms
Electronic structure
DFT Calculations
Molecules
Electronic Structure
dienes
Spectroscopy
photoelectron spectroscopy
electronic structure
Symmetry
symmetry
molecules

Cite this

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title = "UPS Study of Spirosilane",
abstract = "The electronic structure of 2,7-dimethyl-5-silaspiro[4,4]nona-2,7-diene has been investigated byUV photoelectron spectroscopy (UPS). The analysis of the spectra has been performed by DFT andROVGF calculations and comparison with the UPS spectra of related compounds. An unusual '-orbitaldegeneracy in this molecule of C2-symmetry was observed. The spiroconjugation is quenched,and the reasons are discussed",
keywords = "Photoelectron Spectroscopy, Spiroconjugation",
author = "Igor Novak and Branka Kovac",
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UPS Study of Spirosilane. / Novak, Igor; Kovac, Branka.

In: Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences, Vol. 58a, No. 4, 2003, p. 217-219.

Research output: Contribution to journalArticle

TY - JOUR

T1 - UPS Study of Spirosilane

AU - Novak, Igor

AU - Kovac, Branka

N1 - Imported on 12 Apr 2017 - DigiTool details were: Journal title (773t) = Zeitschrift fuer Naturforschung. Section A: A Journal of Physical Sciences. ISSNs: 0932-0784;

PY - 2003

Y1 - 2003

N2 - The electronic structure of 2,7-dimethyl-5-silaspiro[4,4]nona-2,7-diene has been investigated byUV photoelectron spectroscopy (UPS). The analysis of the spectra has been performed by DFT andROVGF calculations and comparison with the UPS spectra of related compounds. An unusual '-orbitaldegeneracy in this molecule of C2-symmetry was observed. The spiroconjugation is quenched,and the reasons are discussed

AB - The electronic structure of 2,7-dimethyl-5-silaspiro[4,4]nona-2,7-diene has been investigated byUV photoelectron spectroscopy (UPS). The analysis of the spectra has been performed by DFT andROVGF calculations and comparison with the UPS spectra of related compounds. An unusual '-orbitaldegeneracy in this molecule of C2-symmetry was observed. The spiroconjugation is quenched,and the reasons are discussed

KW - Photoelectron Spectroscopy

KW - Spiroconjugation

M3 - Article

VL - 58a

SP - 217

EP - 219

JO - Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences

JF - Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences

SN - 0932-0784

IS - 4

ER -