UV angle resolved photoelectron spectra of fluoro and chloromethane using synchrotron radiation

I. Novak, J. M. Benson, A. W. Potts

Research output: Contribution to journalArticlepeer-review

17 Citations (Scopus)

Abstract

Photoelectron asymmetry parameters (β) and partial photoionization cross-sections have been measured for ionization from the molecular orbitals of CH3F and CH3Cl using synchrotron radiation in the photon energy range 19 to 115 eV. Cooper minima are observed in the β spectra of CH3C1 for ionization from orbitals with Cl 3p character. Several shake-up bands observed in the F 2s and Cl 38 ionization energy region indicate a breakdown of the one-electron picture of ionization. The position and relative intensities of the satellite bands are compared with the results of Green's function calculations.

Original languageEnglish
Pages (from-to)225-233
Number of pages9
JournalJournal of Electron Spectroscopy and Related Phenomena
Volume41
Issue number2
DOIs
Publication statusPublished - 1986

Fingerprint

Dive into the research topics of 'UV angle resolved photoelectron spectra of fluoro and chloromethane using synchrotron radiation'. Together they form a unique fingerprint.

Cite this